Modulated synthesis of zirconium-metal organic framework (Zr-MOF) for hydrogen storage applications
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Ren, Jianwei
Bessarabov, Dmitri
Langmi, Henrietta W.
North, Brian C.
Mathe, Mkhulu
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Elsevier
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Abstract
A modulated synthesis of Zr-metal organic framework (Zr-MOF) with improved ease of handling and decreased reaction time is reported to yield highly crystalline Zr-MOF with well-defined octahedral shaped crystals for practical hydrogen storage applications. The Zr-MOF obtained from the modulated synthesis showed high thermal and moisture stabilities with enhanced hydrogen storage capacity. Further study suggests that the modulated synthesis of Zr-MOF may lead to the development of a flow-through synthesis process
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Ren, J.W. et al. 2014. Modulated synthesis of zirconium-metal organic framework (Zr-MOF) for hydrogen storage applications. International journal of hydrogen energy, 39(2):890-895. [https://doi.org/10.1016/j.ijhydene.2013.10.087]