Syntheses of 4‐OH and 5‐OH imidacloprids
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Takahashi, Keisuke
Ikenaka, Yoshinori
Tsurumi, Tatsuya
Inami, Moe
Li, Zui
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Wiley
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4‐OH and 5‐OH imidacloprids, important metabolites of neonicotinoid insecticides, were synthesised in 4 steps starting from S‐methylisothiourea sulfate. The structure of 4‐OH imidacloprid was determined by X‐ray crystallographic analysis. This is the first example of the synthesis of both metabolites independently
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Takahashi, K. et al. 2019. Syntheses of 4‐OH and 5‐OH imidacloprids. ChemistrySelect, 4(24):7343-7345. [https://doi.org/10.1002/slct.201901491]