Kronbauer, Marcio A.Waanders, Frans B.Izquierdo, MariaDai, ShifengWagner, Nicola J.2016-02-052016-02-052013Kronbauer, M.A. et al. 2013. Geochemistry of ultra-fine and nano-compounds in coal gasification ashes: a synoptic view. Science of the total environment, 456-457:95-103. [https://doi.org/10.1016/j.scitotenv.2013.02.066]0048-96971879-1026http://hdl.handle.net/10394/16180https://doi.org/10.1016/j.scitotenv.2013.02.066The nano-mineralogy, petrology, and chemistry of coal gasification products have not been studied as extensively as the products of themorewidely used pulverized-coal combustion. The solid residues from the gasification of a lowto medium-sulfur, inertinite-rich, volatile A bituminous coal, and a high sulfur, vitrinite-rich, volatile C bituminous coal were investigated. Multifaceted chemical characterization by XRD, Raman spectroscopy, petrology, FE-SEM/ EDS, and HR-TEM/SEAD/FFT/EDS provided an in-depth understanding of coal gasification ash-forming processes. Thepetrologyof the residues generallyreflected the rank andmaceral composition of the feed coals, with the higher rank, high-inertinite coal having anisotropic carbons and inertinite in the residue, and the lower rank coal-derived residue containing isotropic carbons. The feed coal chemistry determines the mineralogy of the non-glass, non-carbon portions of the residues, with the proportions of CaCO3 versus Al2O3 determining the tendency towards the neoformation of anorthite versus mullite, respectively. Electron beamstudies showed the presence of a number of potentially hazardous elements in nanoparticles. Some of the neoformed ultra-fine/nano-minerals found in the coal ashes are the same as those commonly associated with oxidation/transformation of sulfides and sulfatesenNanoparticle morphologyHazardous elementsIGCCCoal ashArticle