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dc.contributor.authorVan Zyl, P.G.
dc.contributor.authorBreet, E.L.J.
dc.contributor.authorWilliams, C.S.
dc.date.accessioned2010-05-13T06:06:55Z
dc.date.available2010-05-13T06:06:55Z
dc.date.issued2008
dc.identifier.citationVan Zyl, P.G. et al. 2008. Recover of KAu (CN)2 from granular activated carbon using supercritical CO2. Journal of supercritical fluids, 47(1):31-36. [https://doi.org/10.1016/j.supflu.2008.05.008]en
dc.identifier.issn0896-8446
dc.identifier.urihttp://hdl.handle.net/10394/3004
dc.identifier.urihttps://doi.org/10.1016/j.supflu.2008.05.008
dc.identifier.urihttp://www.sciencedirect.com/science/article/pii/S0896844608001861
dc.description.abstractThe recovery of KAu(CN)2 preloaded onto activated carbon by pure and cosolvent entrained supercritical carbon dioxide (sc-CO2) was investigated using a laboratory-size supercritical extractor. Gold on the carbon surface was monitored by SEM-EDS, while either ICP-MS or AA was employed to detect gold in the corresponding extracts. Recovery was improved by TBP (or TBP-HNO3 adduct) used as a stand-alone extractant or as a cosolvent to sc-CO2, but no more than 10% of the preloaded gold could be extracted, contrary to higher yields of recovery from other types of matrices claimed in the literature. This is ascribed to a surface related limitation in view of observations made on modifying the surface area of the activated carbon
dc.language.isoenen
dc.publisherElsevieren
dc.subjectKAu(CN)2
dc.subjectActivated carbon
dc.subjectSupercritical carbon dioxide
dc.subjectTributyl phosphate
dc.titleRecover of KAu (CN)2 from granular activated carbon using supercritical CO2en
dc.typeArticleen
dc.contributor.researchID10710361 - Van Zyl, Pieter Gideon
dc.contributor.researchID10179402 - Breet, Ernst Lodewyk Johannes


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