| dc.contributor.author | Ren, Jianwei | |
| dc.contributor.author | Bessarabov, Dmitri | |
| dc.contributor.author | Rogers, Dave E.C. | |
| dc.contributor.author | Segakweng, Tshiamo | |
| dc.contributor.author | Langmi, Henrietta W. | |
| dc.date.accessioned | 2018-06-26T09:48:54Z | |
| dc.date.available | 2018-06-26T09:48:54Z | |
| dc.date.issued | 2014 | |
| dc.identifier.citation | Ren, J.W. et al. 2014. Thermal treatment induced transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5). International journal of materials research, 105(1):89-93. [https://doi.org/10.3139/146.110994] | en_US |
| dc.identifier.issn | 1862-5282 | |
| dc.identifier.uri | http://hdl.handle.net/10394/28087 | |
| dc.identifier.uri | https://doi.org/10.3139/146.110994 | |
| dc.identifier.uri | https://www.hanser-elibrary.com/doi/abs/10.3139/146.110994 | |
| dc.description.abstract | A simple thermal treatment induced transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5) is reported. Phase crystallinity, pore characteristics and hydrogen storage capacities of the resulting crystals were investigated. It is shown that the structural transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5) could be induced by simply employing the optimal thermal treatment conditions of 200 °C for 48 h in open air. The resultant relatively lower specific surface area of MOF-5 crystals compared to MOF-69c was in agreement with the increased pore diameter and decreased hydrogen storage capacity at 1 bar and 77 K | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Hanser | en_US |
| dc.title | Thermal treatment induced transition from Zn3(OH)2(BDC)2 (MOF-69c) to Zn4O(BDC)3 (MOF-5) | en_US |
| dc.type | Article | en_US |
| dc.contributor.researchID | 22730389 - Bessarabov, Dmitri Georgievich | |
