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dc.contributor.authorOnwudiwe, Damian C.
dc.contributor.authorMugo, Jane N.
dc.contributor.authorHrubaru, Madalina
dc.contributor.authorHosten, Eric
dc.date.accessioned2016-09-01T12:29:21Z
dc.date.available2016-09-01T12:29:21Z
dc.date.issued2015
dc.identifier.citationOnwudiwe, D.C. et al. 2015. Bis diallyl dithiocarbamate Pt(II) complex: synthesis, characterization, thermal decomposition studies, and experimental and theoretical studies on its crystal structure. Journal of sulfur chemistry, 36(1):36-47. [http://www.tandfonline.com/toc/gsrp20/current]en_US
dc.identifier.issn1741-5993
dc.identifier.issn1741-6000 (Online)
dc.identifier.urihttp://hdl.handle.net/10394/18496
dc.identifier.urihttp://dx.doi.org/10.1080/17415993.2014.960418
dc.identifier.urihttp://www.tandfonline.com/doi/full/10.1080/17415993.2014.960418
dc.description.abstractPlatinum dithiocarbamate (DTC) complex has been synthesized from the ligand diallyl DTC, and its structure was established from elemental analysis, IR, NMR, and single-crystal X-ray analyses to be Pt[S2CN(C3H5)2]2. The thermal properties were studied using a simultaneous thermal analyzer, and showed two main steps of decomposition. The structural geometry analysis was determined using X-ray diffraction and Density Functional Theory (DFT) calculations. The single-crystal X-ray analysis showed that the complex has a square planar geometry. The diallyl groups of the DTC ligands are not symmetrical making the complex non-centrosymmetric, and the complexes are stacked with intermolecular ring–ring interactions. The DFT calculations were performed to obtain the theoretical information and compared with the experimental data obtained from the experimental crystal structureen_US
dc.description.sponsorshipNorth-West University and the Chemical Research Beneficiation (CRB) Research Focus Area. The work presented in this paper is based on the research supported by the National Research Foundation of South Africa.en_US
dc.language.isoenen_US
dc.publisherTaylor & Francisen_US
dc.subjectDiallyl dithiocarbamateen_US
dc.subjectplatinumen_US
dc.subjectcrystal structureen_US
dc.subjectthermal analysisen_US
dc.subjectconformational analysisen_US
dc.titleBis diallyl dithiocarbamate Pt(II) complex: synthesis, characterization, thermal decomposition studies, and experimental and theoretical studies on its crystal structureen_US
dc.typeArticleen_US
dc.contributor.researchID23567856 - Onwudiwe, Damian Chinedu
dc.contributor.researchID25678574 - Mugo, Jane Ngima


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