dc.contributor.author | Cruywagen, J.J. | |
dc.contributor.author | Kriek, R.J. | |
dc.date.accessioned | 2014-07-30T12:48:36Z | |
dc.date.available | 2014-07-30T12:48:36Z | |
dc.date.issued | 2007 | |
dc.identifier.citation | Cruywagen, J.J. & Kriek, R.J. 2007. Complexation of palladium(II) with chloride and hydroxide. Journal of coordination chemistry, 60(4):439-447. [https://doi.org/10.1080/00958970600873588] | en_US |
dc.identifier.issn | 1353-7903 | |
dc.identifier.issn | 1469-9419 | |
dc.identifier.uri | http://hdl.handle.net/10394/10968 | |
dc.identifier.uri | https://doi.org/10.1080/00958970600873588 | |
dc.identifier.uri | https://www.tandfonline.com/doi/abs/10.1080/00958970600873588 | |
dc.description.abstract | Complex formation of Pd(II) with chloride and hydroxide has been investigated by spectrophotometry at 25°C and ionic strength 1.0 M. For the chloride complexes [PdCl n (H2O)4− n ]2− n (n = 0–4), the formation constants, β n , have been determined and the values are: log β1 = 4.47, log β2 = 7.80, log β3 = 10.18 and log β4 = 11.53. The formation of mixed chloro-hydroxo complexes, [PdCl p (OH) q ]2−, has been investigated at three chloride concentrations, 1.0, 0.5 and 0.2 M over the pHc range 4–12. The average values determined for the formation constants, β pq , where p and q refer to the number of chloride and hydroxide ions in the complex, are: log β31 = 16.48, log β22 = 20.63, log β13 = 24.02 and log β04 = 26.23. Molar absorption spectra for all the complexes in question have been obtained. | en_US |
dc.language.iso | en | en_US |
dc.publisher | Taylor & Francis | en_US |
dc.subject | Stability constants | en_US |
dc.subject | Palladium(II) chloro complexes | en_US |
dc.subject | Palladium(II) hydroxo complexe | en_US |
dc.subject | Palladium(II) mixed chloro-hydroxo complexes | en_US |
dc.title | Complexation of palladium(II) with chloride and hydroxide | en_US |
dc.type | Article | en_US |
dc.contributor.researchID | 13238477 - Kriek, Roelof Jacobus | |