Browsing by Subject "Grubbs-type precatalyst"
Now showing items 1-4 of 4
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Catalysis of linear alkene metathesis by Grubbs-type ruthenium alkylidene complexes containing hemilabile α,α-diphenyl-(monosubstituted-pyridin-2-yl)methanolato ligands
(Beilstein-Institut, 2019)Four new Grubbs-type precatalysts [RuCl(H2IMes)(O^N)(=CHPh)], where [O^N = α,α-diphenyl-(3-methylpyridin-2-yl)methanolato, α,α-diphenyl-(4-methylpyridin-2-yl)methanolato, α,α-diphenyl-(5-methylpyridin-2-yl)methanolato and ... -
A DFT computational study of phosphine ligand dissociation versus hemilability in a Grubbs-type precatalyst containing a bidentate ligand during alkene metathesis
(Taylor & Francis, 2008)Using density functional theory, the metathesis reaction of 1-octene in the presence of a Grubbs-type ruthenium alkylidene complex bearing a chelating pyridinyl alcoholate ligand, [RuCl(L)(O∧ N)( = CHPh)] (L = H2IMes or ... -
Separation of homogeneous catalysts using Organic Solvent Nanofiltration
(North-West University (South Africa), 2016)One technology that has shown in literature to have great potential for separating homogeneous catalysts from their reaction mixture is organic solvent nanofiltration (OSN), which is a pressure-driven, membrane-based ... -
Synthesis and application of novel ruthenium catalysts for high temperature alkene metathesis
(MDPI, 2017)Four pyridinyl alcohols and the corresponding hemilabile pyridinyl alcoholato ruthenium carbene complexes of the Grubbs second generation-type RuCl(H2IMes)(O^N)(=CHPh), where O^N = 1-(2′-pyridinyl)-1,1-diphenyl methanolato, ...